In general amps is amps, so a breaker will perform per its thermal tripping curve regardless of AC or DC.
However the effect of short circuit amps are different. The magnetic portion of an AC breaker will usually not react properly to a DC fault. Check with the manufacturer for the adjustment factors.
And as others have pointed out, actually clearing a DC arc is often very difficult for an AC device. Most AC breakers have different voltage and AIC ratings when used on DC.
That said, most of the QO family of breakers are rated for use up to 48VDC.