Working space is not intended to be the "hazard limit." It is not a matter of your being at risk while in the space, and being safe once you are out of the space. That is not its intent. The presumption is that you are inside the working space, actually working, when an event occurs. You need to be able to get to a door. You must certainly be walking through the working space in which you are standing, to get to a door.
My notion of a violation of this rule would be if as you stand in front of the equipment, with the one and only exit door to your right, and if in order to get access to the inside of the panel the door that you need to open is hinged on its right side. Thus, with the panel door open, the door is now located between you and the exit door. I would call that "obstructed."
It is worth noting that the rules changed with the 2008 NEC.