The rated secondary current will be 75,000 VA divided by 208 volts and divided again by the square root of three. That gives you about 208 amps. You are allowed to size the secondary overcurrent device as high as 125% of the rated current. My reference is table 450.3(B). That results in 260 amps. So using a 250 amp breaker is acceptable. So far, so good.
However, per table 310.15(B)(16), an aluminum 1/0 XHHW is only good for 120 amps. So that will not work. You need at least 300 MCM in that type of wire. So someone made an error on the drawings.
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