Brown-Orange-Yellow for 480V and Black-Red-Blue for 208V is a convention, not a code requirement. You can use Black-Red-Blue for 480V and Pink-Purple-Cyan for 208V if you wish.
As
@infinity notes, there is a code requirement that if you have different voltage systems in the same building you have to identify them, meaning that you need to be able to tell 208V and 480V apart. So if you have a building that only has 208V in it, you can use your existing BOY feeder and not change a thing. But presumably the building has 480V in it, and that is why you have a spare BOY feeder.
The simplest thing to do is to use colored tape at all of the terminations of the existing conductors, and 're-identify' them Black-Red-Blue (or whatever 208V colors are in use).
I agree with
@wwhitney that re-identifying one 'hot' color to another 'hot' color doesn't have size restrictions.