250.53(A)(2) requires the rod to have a supplemental electrode of a type specified in 250.52(A)(2) thru (8). That notably excludes 250.52(A)(1), which is the water pipe. So the water pipe cannot supplement the rod.
250.53(D)(1) requires the water pipe to have a supplemental electrode that, if a rod, pipe or plate, complies with entirety of 250.53(A), which in turn requires the additional supplemental electrode that is not the water pipe.
In other words, they very deliberately wrote it to require two rods to supplement the water pipe if you don't have one of the other things like a ufer. Not easy to follow, but very clear once you do.