Other than the cases already listed, I know of two other design issues where a 4P CB could be used (typically are not - but could be). They are a bit out of the ordinary, but I have seen them often enough - cause this is the kind of stuff I work on.
Solidly grounded 480/277W, fed with multiple paralleled generators:
The issue is if a generator has to be taken off line for maintenance, one does not want the neutral still connected to system neutral. If the system develops a ground fault, the neutral can be elevated to line potential until the faulted circuit CB trips. And this really irritates the tech that has her hands in the alternator - possibly only for fractions of a second, but still not good.
The solution is usually to mount a disconnect on the gen to isolate the neutral fromn the system neutral. N-G bonds are in the switchgear. Often a standard 3 pole disconnect used with one pole used as an auxilary to inhibit the gen start when open.
High Impedance grounded 480V, paralleled transfromers:
If one transfromer is to be pulled off-line for service, the transformer neutral must be disconnected from the grounding resistor. A system ground fault will elevate the transformer neutral and leave it there until the fault is removed. That really really iritates the techs.
Again, a disconnect is used in the neutral to grounding couductor connection, with one pole used to trip the primary CB if the disconnect is opened.
These are design issues, not NEC issues.
ice