You might supply more info. Where is the 800A 480/277 being sourced from. Since I assume it is 3 phase w neutral you need 800A per phase so run 2 500 kcmil in parallel for each phase in 4" PVC conduit. A little overkill but ok. Same for neutral.
For the step down trafos here is some info. This is what to use to get a 240/120 from the 480/277
This explains all voltage derivations with hi leg etc.
https://www.youtube.com/watch?v=dlscWJRm38M
I assume you may need 240 but if not the info will still help. The derived neutral will be very low current if you do a good job with balancing. If you want super big margin make derived neut same as phase. You will connect it to ufer(concrete encased rebar) ground if you have that.
This is Mike Holt explaining so well the derived neutral in Delta to Y which describes a 400A service dry trafo
https://www.youtube.com/watch?v=a8LjxEtd8N8
Let me know more about how it is going since I have a similar job and I want to compare notes with you......I have to run many many 230V indoor units (HVAC) from 277/480 like you. The outdoor units all are 480 3 phase.