Bingo.
If the heaters are the ONLY load, then they will likely not care if it's a corner grounded Delta (or ungrounded with GFP). But in addition to the load itself, not all CIRCUIT BREAKERS are rated for 480V delta. Many small inexpensive 480V breakers are "slash rated" meaning they can ONLY be used where the source is a grounded Wye 480/277V system. If you can find a transformer with a secondary that is 480Y, that's a better choice all around.
Also, transformers used for step-up must now by Code be identified for that use by the manufacturer. It doesn't need to be on the nameplate itself (but that helps), it can be identified as such in the data sheets but if you are having it inspected, have those data sheets with you at inspection to avoid a call back. One of the reasons behind this by the way is because of the potential effects of compensating techniques used in the transformer design resulting in undesirable effects, which is what Besoeker was referring to in his post. That then likely means the transformer you picked would not have been to Code, because it likely was designed for step-down use only.