EP,
I appluaud your efforts to do the right thing, but remmember working on 480V panels is much different than working on 3000A switchgear, the fact that people dont understand that (Because they falsly believe all 480V has about the same hazards) is why OSHA has specific qualification requirement for working in dist substations and why 70E has specific training requirements.
If you dont understand the requirements, which as you said, you dont, you are not qualified to do this type of work, your employer can face monster fines if you were injured on the job. Your employer is responsible and required to provide you with the required training, not just a copy of the 70E.
I will be happy to recommend several quality training programs and the requirements for you to take to your boss to get this training, and the right PPE for what you are being asked to do.,