Funny you say that. There is an effort underway by some folks in the high temp, plenum cable industry to discredit all zinc alloy fittings when used with EMT or RIGID conduits. They have made a nice YouTube video showing zinc fittings melting (at 720F+!!) and the cables inside exploding in fire...:roll: ( I have been told that a large chemical corporation is behind this video to get the code to accept their new, plenum rated, high-temp cable for use without conduit raceways..)
http://www.youtube.com/watch?v=SYgLVshgoTs&feature=channel
My point is that paper burns at 451F, and if your building reaches that level of heat, your electrical system is most likely toast as well. Therefore it is irrelevant that the fittings are melting at higher temperatures when compared to steel counterparts. They don't even discuss the other parts of the system that would be affected - like anchors, aluminum conduit bodies, duct seal, etc, etc..)