Both outside legs?
The transformer, being Y has three outside legs. Three phases.
That would give you a line current capacity of about 625A. (Assuming 208V line to line.) Possibly greatly more than you need for the CNC machines. But what else does it feed?
You simply can't calculate it that way.
Transformer losses are normally quite small. They come in two kinds. Iron loss (Fe) and copper loss (Cu).
The Fe loss is typically less than 1% - for loss calculations I work on 0.7%. The Cu loss might be about 1% at the full rating of the transformer. And it is square law with current. Half the current is quarter of the losses. In your case, if you are running your 225kVA unit at about 10% (1/10) loading, you'd be down to 1% of full load Cu losses. That is 1% of 1%.
In short, your 225kVA transformer losses are pretty unlikely to be burning a ton of electricity. Reducing the rating and/or rebalancing would be, at best, tinkering around at the margins for energy savings.