You're confusing UL requirements and NEC requirements. While UL only requires a GEC for inverters that ground a DC conductor, the NEC requires an electrode and GEC for grounding equipment, and for grounding solar systems, and in 2014, for grounding solar arrays (690.47(D)). Note that under the 2014 NEC the GEC for a solar system (i.e. inverter) is allowed to be sized to 250.122 but the GEC for an array is required to be sized to 250.66. Don't try to make sense of that, by the way.
The premises electrode is the electrode on the separate building, as far as I see it. See 250.32. As far as I can tell, the term 'premises electrode' is used no where else in the NEC other than this 690.47(D) exception. Your use of the term 'premises electrode' to refer, I presume, to the electrode back at the service, contains an implicit interpretation that I believe you'd be well advised to abandon. It helps nothing and encourages you to create a less safe installation. Blame the CMP for using imprecise language in 690.47(D), (not to mention putting the section back in the first place). What I believe they meant by premises electrode, as Brooks describes, is any GES that is already at the structure.
The 'safest' arrangement, to my understanding, is to have connections between electrodes made without going through any other equipment, and to have them underground or as close to the ground as possible. (Mind you, the NEC already contains requirements that undermine these goals, in order to meet other goals, but notwithstanding, you do the best you can.)
If your separate building has an AC subpanel then it is already required to have an electrode system per 250.32. I'm pretty sure the safest thing is not to add another electrode per 690.47(D) that is more than 6ft away, and then to connect these two electrodes as follows: a GEC between first electrode and subpanel, connected to an EGC between subpanel and array up to the roof, connected to a different GEC down from the roof to the second electrode. That is multi-point grounding for one building which creates precisely the situation Mike Holt warns against. Rather, if you're worried about the GEC requirement in 690.47(D), then size your green wire between the roof and subpanel to 250.66 and call it a combined GEC/EGC. That way you can fulfill both 690.47(D) requirements and 250.32 requirements without creating an unsafe situation.