Generally I will get the mfg cb manual, the protective relay manual, and the control interconnect diagram. Usually these have sections that describe the contacts, operation and timing.
With the manuals in hand, it a matter of puzzling through the schematic/interconnect diagrams. Occasionally I have had to call the mfg tech support or engineering cause something is not clear. I usually do better with engineering.
A couple of things to get started:
Medium voltage cbs generally have to have external control power to trip, although they will likely have a mechanical actuation buttons as well
52a contacts close on CB closed. 52b contacts close on CB open
SF6 breakers will have pressure switches that will either open the CB on low pressure, or inhibit opening the cb on low pressure.
There will be aux contacts that remove power from the trip and close coils as soon as the cb activates.
There will likely be two trip coils
There may be a close coil and a holding coil or just a close coil.
Ther will be a spring charging motor with attendent control contacts.
There is likely an anti-pump ckt
cf