Actually it is not a constant though many call it such.
It's a value based on the conductivity of a material. Units are Siemens, and the reciprocal of resistivity. A conductor of uniform cross section has a resistance proportional to its resistivity and length and inversely proportional to its cross-sectional area.
Go to Chapter 9 Table 8. Pick any conductor and multiply its cmil area by its resistance per 1,000 ft and divide by 1,000.
The units of K are actually cmil-Ohms/ft, which are dimensionally the same as Ohm-meters, the unit for resistivity.
K is simply another version of rho for resistivity, that you would look up in a Physics handbook. The difference is that it is expressed with cmil instead of m^2 as the unit for area, and ft instead of meters as the unit for length.
Conductivity is the reciprocal of resistivity, just like conductance is the reciprocal of resistance. The word ending in "-ivity" is a material property, independent of the geometry of what you make out of the material. The word ending in "-ance" is a specific component's property, which does depend on geometry. Conductance has units of Siemens (originally mhos). Conductivity has units of Siemens per meter.
Usually the electrical world thinks in terms of resistivity, while the thermal world thinks in terms of conductivity. Thermal conductivity has nothing to do with Ohms, Volts, or Amps, but instead uses power and temperature units.