Gus,
As far as I know all of the parts of the system, including any type of connections and splices must comply with 110.10. As I see it, any connector that does not have a short circuit rating cannot be used in any NEC application.
If the power distribution blocks are listed to a standard that only applies to load side installations, then the use of those blocks on the line side of the service disconnect would be a 110.3(B) violation. That being said, I would not see a problem using the distribution block on the line side of the service OCPD, as long as the block had a SCCR rating equal to or greater than the available current at that point in the circuit.