From a design standpoint, General Duty switches do not have to pass the more rigorous switching duty testing that Heavy Duty switches do. The design criteria for HD is I believe 15,000 operations at up to 5 per hour at full rated capacity. GD switches are 10,000 operations at 1 per hour. The reason you don't see GD safety switches in 600V ratings is because it is generally accepted that anything that needs 480V and up will not be a light duty residential or commercial application.