225.30 Number of Supplies.
A building or other structure that is served by a branch circuit or feeder on the load side of a service disconnecting means shall be supplied by only one feeder or branch circuit unless permitted in 225.30(A) through (F). For the purpose of this section, a multiwire branch circuit shall be considered a single circuit.
(A)-(F) not applicable here.
The building shall be supplied by
Only One Branch circuit. Supply Can be a MWBC. Once you get to the other building it can be divided, don't see the wording as saying you can divide before you get to the building. The "feeder or branch circuit" is not the breaker but the wiring between the buildings.
See definition of a MWBC:
Branch Circuit, Multiwire. (Multiwire Branch Circuit)
A branch circuit that consists of two or more ungrounded conductors that have a voltage between them, and a neutral conductor that has equal voltage between it and each ungrounded conductor of the circuit and that is connected to the neutral conductor of the system.
I see the term "a neutral conductor", That to me says it is a singular neutral. Combine that with 225.30 I read that as only one neutral between the two structures.