Another way to vent if the room, if it is closed up. Provide a non hazardous ducted blower fan, ducting clean air from a different clean source area into the room.
Then provide a duct or exhaust grill, large enough to exhaust the supply the fresh air being pumped into the room.
A mechanical contractor might be able to assist you in sizing an appropriate supply fan and exhaust duct or louver opening.
A 4" pipe sounds awfully small for a sewage pump room. An exhaust fan doesn't work well if it is not provided with a supply air source
Paint mixing rooms were often ventilated in this manner,. Supply pressurized clean air in, and an exhaust opening to a safe discharge area.