Silly me. I always thought that higher voltages meant lower amperage. You know... like transmission lines use 7200v and up so the amperage is much lower.
That's true when the equipment is built to natch the voltage. When talking about delivering a given power, the P = E x I math applies. To deliver a given power, current varies inversely with voltage. Also, loads like motors use less current when the voltage increases (within its design voltage range).
When talking about applying a different voltage to equipment with no change to the equipment, then the I = E / R Ohm's Law math applies. The current varies proportionately with applied voltage. This describes most electrical loads which behave as resistive loads do. If the voltage increases, so does the current.
I guess I should rewire my house for 5 volts so I can use tinsel wire.
If you apply only 5v to loads designed for 120v, so little current would result that you probably could. 120 / 5= 24, so 1/24 as much current would flow at 5v compared to 120v.
On the other hand, if you want the same amount of power on 5v as you would on 120v, you'd have to be able to supply 24 times as much current, so you'd need very heavy wire.
Look at your car wiring. Battery and spark-plug cables are about the same diameter, but battery cables are mostly conductor, while spark-plug cables are mostly insulation.
Electricity is transmitted at high voltages over distances because insulation is cheaper than conductor, and more importantly, voltage drop is dependent on current, not voltage.
By the way, 7200v is relatively low for even primary distribution. Transmission voltages are in the 100Kv and up range; some long-distance lines are into the megavolt range.