That's not the way I'm reading it. It says if the pipe, rod, or plate meets the 25 ohm, then no additional electrode needed. So if the pipe didn't meet it, then a rod added would satisfy that. It doesn't say a single rod is not an electrode.
One pipe + one rod = satisfied
(2) Supplemental Electrode Required. A single rod, pipe, or
plate electrode shall be supplemented by an additional electrode
of a type specified in 250.52(A)(2) through (A)(8). The
supplemental electrode shall be permitted to be bonded to one
of the following:
(1) Rod, pipe, or plate electrode
(2) Grounding electrode conductor
(3) Grounded service-entrance conductor
(4) Nonflexible grounded service raceway
(5) Any grounded service enclosure
Exception: If a single rod, pipe, or plate grounding electrode has a
resistance to earth of 25 ohms or less, the supplemental electrode shall
not be required.