Well....I am definitely not an expert on PPE rules, but I have a story (of course...). Working on a 277/480 pump station with a fused disconnect panel that also contained control circuitry. Standing in water in a dark, cramped control house. I had the water tech (gorilla, really) pull the disconnect handle to off and open the door while I grabbed my tools. Assuming all was dead (my bad), I started jiggling wires to see if we had a loose connection. Heard a relay "click"! What!!! Checked with my meter (no gloves) and had full voltage everywhere. Turns out, the gorilla had pulled down the handle and the contacts were rusted shut, so all he did was break the mechanical linkage from the handle to the disconnect. No excuses...just stupid. The correct procedure was to wear PPE to test for dead, tag any source breakers and only then remove any PPE. Why didn't I??? The moon suit was too hot, hard to see, cumbersome and all I was doing was checking for loose connections. I could probably come up with a few more excuses, but you get the idea. The ONLY way to know if it's dead is to test it, and the ONLY safe way to test it is with a meter and appropriate PPE. Nuff said. Rules aren't just for the other guy!
High voltage linemen have a saying..."Identify, isolate, test and ground....if it isn't grounded, it isn't dead!" Good advice.
Another old saying..."There are old electricians and bold electricians, but there aren't that many old, bold electricians." Sorry if I'm preaching, but the hard way is a bad way to learn. Don't ask how I know!:ashamed1: