You don?t need to go back too many Code cycles to see that Intrinsically Safe and Nonincendive have only received formal definition fairly recently. More importantly, the underlying definitions are outside the NFPA altogether. The ?official? descriptors of both systems are ANSI/ISA 12.12.01 and ANSI/ISA RP 12.06.01.
In the early years, as these wiring systems were developing, they were almost treated interchangeably. Ultimately, the ISA took control of these wiring systems.
As I said earlier, both systems require a Control Drawing. If you want to treat thermocouples as Intrinsically Safe, you will need a manufacturer?s support to do so.