I have never seen an outer nylon jacket on XHHW.
That is XHHN I have never seen it but it got added to the code a few cycles back.I assumed XHHW had the same nylon coating THHN gets, but it doesn't look like the is the case
Yeah keep specifying XHHW you might even give more EC's the right idea, I got the idea from a municipal project EE about 20 years ago and started using it occasionaly on commercial design / builds - just for for long outside stuff.especially when we're going with the lowest bid, it just makes me a bit uneasy. You know how 'field experience' can really swing wildly from one crew to the next.
Outdoor stuff is typically longer pulls, subject to harsher conditions generally and during wire pulls more likely to get some dirt or grit in the conduit. Conduits then are more likely to be water logged for months after storm with who knows what in the water, around here I have seen UG conduit just bubble water out of a vault, for the slight cost difference you get a much better install.
Its a easy option to add to a quote even if its not in the specs.