I'm not an expert on transformers, and I can't fully answer your question. Hopefully an EE will chime in here. But a couple points...
1) I think you should still be thinking of the 480delta side as the primary and the 208/120Y side as the secondary. With grid-interactive inverters we don't switch around our 'line' and 'load' terminology or connections - the grid is always still the 'line' - and I don't think we do that with transformers either. If you have any loads on the 208Y side that could operate at night then the XF will be operating as a step-down instead of a step-up. Maybe you won't have any significant loads, but you could. And I assume you'll have some small line-neutral loads from monitoring devices, and from a code point of view I think those count. So I would assume the XF has to operate safely as a step-down as well as a step-up, and interpret code as if it were a step down, (or both, if that's possible). Maybe others here will disagree, but I would certainly say you need to clarify the issue at the beginning.
Put another way, if this were an existing, properly installed step-down serving loads, you would be able to connect your solar without asking this question. So create that, then install your solar.
2) If you had a 208/120Y service, and you stepped up for a 480V application, I believe you would not ground the neutral of the transformer because that would be duplicating the neutral-ground bond at the service and creating objectionable current. But that is NOT your situation, right? So that particular reasoning wouldn't apply (although some other reason might). Your 208/120Y side is an SDS and would be grounded accordingly, no?
3) If you're using Enphase inverters, the neutral is also required for communication with the Envoy monitor, so it's definitely necessary.