The issue seems to have been isolated to overloading, and unlikely arc fault (I did eliminate all back stabs in the process and rewire all receptacles to help eliminate any potential arc issues). Although, the old breakers did not trip under the same loads (which is why I was called back out), moving offending appliances to the other SABC produces identical behavior, indicating that it is either the load or appliances themselves, and not the circuit and breakers. And the NPRs are high enough to throw it. But it does appear that the new breakers blow at a smaller amperage as this is new - and that's not necessarily bad, it just is. So the kitchen appliances need to be configured accordingly.