Great, can we now agree that, without considering the exceptions, 230.90(A), gives us a method for determining the size of the overcurrent (again, just overload) protective device based on the results of 230.42?
You are conflating two separate issues.
Concerning conductor sizing, the following indicate that conductors shall have an ampacity of 125% of continuous and 100% of non-continuous loads:
210.19(A)(1)(a)
215.2(A)(1)(a)
230.19(A)(1) (service entrance conductors)
These sections specify a
minimum conductor size based on the load.
The code specifies similar requirements for overcurrent protection for conductors and equipment in:
210.20
215.3
But I can't find any such requirement for service equipment in Article 230 Part VII (or part VI for that matter even that is only for disconnect rating).
These sections specify a
minimum OCPD size based on the load.
Section 230.90(A) relates to
overcurrent protection of the conductors, not to minimum size. Just as Article 240 relates to
overcurrent protection of feeder and branch circuit conductors, not to minimum size. Overcurrent protection of the conductor, and minimum size of the conductor are two separate issues. Both must be met in a proper installation.
As a for instance...let's say you had service conductors with a load of 200A continuous. If you look at 230.42, you find you need a minimum conductor size with an ampacity of 250A. If you look at 230.90(A), it says the OCPD must have a rating not greater than the ampacity of the conductor. That would be anything 250A or smaller, so a 225A c/b would comply with 230.90(A). A 175A c/b would comply with 230.90(A), etc.
There is nothing in Article 230, as you pointed out in your original question, that establishes a
minimum OCPD size for the service entrance conductors. You have to look elsewhere in the Code for that.