For a 480D : 208Y/120 transformer, energized only with 480V single phase on the C-A primary coils, when it is unloaded, won't the voltages need to be symmetric about the B primary side connection? So 240V A-B and 240V B-C on the primary side, as there is nothing to drive the floating B point closer to A vs C. Or can simple manufacturing variations break the symmetry enough to significantly move the B voltage point away from the midpoint?
Then if symmetry does hold, the L-L voltages on the secondary become 180V, 180V, and 0V, while the L-N voltages become 120V, 60V, 60V. You can visualize the standard delta-wye diagram of voltage vectors, and as you collapse one point of the primary side triangle to the midpoint of the opposite side, two legs of the secondary wye flatten out to be along the same line as the third leg, opposite in direction and half as long.
Cheers, Wayne