I might be able to add some clarity here. Fire pump feeders (inside the building only) are required to hold a 2 hour fire resistive rating. There are several ways of doing this.....encased in 2 inches or more of concrete, fire resistive cable system or a listed protective system (an assembly of sorts). There is an exception in the NEC that states the fire rating is not required INSIDE the room they originate in (the fire pump room). So if you're inside the building, and not in the fire pump room, a 2 hour fire resistive rating is required on the feeders. Someone above mentioned MI cable, which is good but there are several others out there. MI is kind of the musket or rifles now. Works but it's hard, slow and not accurate. If you are going to use a fire resistive cable system, including MI, then Article 728 will apply and will trump the rest of the code if in conflict. 728 will direct you to follow the systems "listing" which is actually a UL document called an FHIT XXX. XXX is the system number. These can be found on UL's Product IQ website for free. Just register an email address and create a password, no cost. Then in the search menu, type FHIT and a whole lot of stuff pops up. All of those are "systems" that can be used. MI for example is FHIT 1850, but there are many others that are less expensive and easier to use. No active FHIT document....don't go near it as it's not 728 approved. Those documents will tell you what materials you must use, and some will be brand name specific (like conduits and couplers). And it will tell you how to install it. In essence, Article 728 which trumps the rest of the NEC will tell you to follow the FHIT to the letter or rather the FHIT is the golden rule. And trust me, deviating on any of the materials listed/required in the FHIT will violate the rating, so don't. I get asked all the time about approving this or that type of conduit that isn't listed on the FHIT, and I say nope, it has to come out and be replaced by the right stuff.
I can tell you that if installing a 2 hour fire resistive cable system......rigid conduit isn't going to work and not allowed (for feeders at least). Rigid has zinc on the ID which negatively affects the performance of those systems. Not to mention when testing at UL, rigid is heavy and will sag under the 1850 deg F test which can cause shorting of the wires inside as they come under tension. Rigid is a no no in that game. EMT's can be used, RTRC's can be used and there are some MC type cables as well.
So, in the fire pump room or outside the building, nothing outside of normal is required. But traversing through a building (not in the pump room) a 2 hour fire resistive rating IS required. How you go about achieving that rating is up to you. On new construction, I would go with concrete encasement whenever possible. Remodel or when concrete is not an option, I would go with a cable system (RHW-2 then MC followed by MI), in that order based on costs. Lastly I would go with assemblies, the most expensive option.