I respectfully disagree, but must admit that this is a hunch on my part.
The impedance of the energizing circuit (induction, leakage through the air, etc. between electrical wires and the signs) is _very_ high; the sign support post is probably buried in concrete for a couple of feet, and even if this ersatz 'grounding electrode' has thousands of ohms to ground, the potential of the signs should be that of ground. My gut is that improving the 'grounding' of the signpost won't change the shocks in the slightest, or will perhaps make these shocks worse.
I would expect that the bucket truck (sitting on rubber wheels) or the worker (standing on what is perhaps a fiberglass ladder or in poorly insulating shoes) is being energized relative to the _grounded_ signs. In other words, voltage is being induced on the worker, who is then touching a grounded sign and getting shocked. In this case the solution is not grounding the sign further, but somehow grounding the truck or the worker before they touch the sign.
Perhaps something as simple as a ground wire reel used in aircraft fueling, run from the truck to the signpost.
The risk that I see is in attaching this grounding clamp, because if the sign really is energized and not well grounded (say a street light with an insulation fault), then attaching the grounding clamp could make for a very messy situation.
-Jon