It depends on how the buck-boost was wired. A single transformer wired 208V to 240V would have the common 'hot' leg which would be 120V to neutral.
However if, as in a previous thread, someone used two transformer each connected to boost the 120V, then neither 'hot' leg would be at 120V to neutral. This is why I mentioned 2 legs of a star, or wye, connection in my post.