190903-2000 EDT
What is being described in post #1 is an arc with unidirectional current flow. Most likely in air. The negative electrode emits electrons (see work function at
https://en.wikipedia.org/wiki/Work_function ). I believe the described plasma, to a substantial extent, is formed from ionized gas. However, with heat developed there is some vaporization of material from the anode (positive electrode), ionization of the material, and transfer of the material to the cathode.
A lot of work was done in the past to select or create materials for switch contacts to minimize metal transfer. Silver cadmium oxide has better high current capability than pure silver, but has poor low voltage characteristics because of contact resistance that is not broken down at low voltages. Most electricians don't know this and make some bad substitution mistakes. The same relay with silver cadmium oxide contacts will have double the contact rating at 120 V as will pure silver contacts, 10 A vs 5 A.
If you look at a relay contact that has switched an inductive load of only 1 A at 107 V DC for possibly 100,000 or less cycles you will find a conical mound on the cathode contact and a conical hole in the anode contact.
This was always a problem for automotive ignition contacts. In the early 1940s Henry Ford and Emil Zorelein invented a distributor that alternated the direction of current flow thru the breaker points every mechanical cycle. I would expect they had worked on ideas for this much earlier. This never went into production. Later in the early 1950s a Ford engineer invented breaker points with a hole in the center of the cathode contact. This greatly reduced the build up of the cathode cone and thus increased breaker life. This went into production.
See "Fundamentals of Engineering Electronics", William G. Dow, John Wiley, 1937 and 1952, Chapters XII, XV, XVI, and XVII for discussions on spark, arc, and plasma.
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