Hi Don,
That informational note is just telling you "one source" for temperature data--which implies it is not the definitive source or will cover all conditions. I don't see any NEC definition of ambient temperature. So here's the definition of ambient Google selects:
Based on that definition, it is clear to me that ambient temperature at ground level and ambient temperature on a rooftop are two different things. So if the ASHRAE Handbook includes statistical temperature data collected at, say, 5 feet above a flat rooftop, that would be appropriate to use for installing conductors 5 feet above a flat rooftop. If it only has data collected at ground level, then that source would only be appropriate for use at ground level.
Cheers, Wayne