I don't think the outgoing conductors to the outbuilding that is not a dwelling unit would be able to be considered service conductors anymore as your first OCPD is in the panel, so by definition those are feeders.
You apparently can have a service disconnect in the same compartment as an emergency disconnect so no issue with the feeder.
But that would be for only two of the 8 breaker spaces, since your cant have more than one service disconnect in an enclosure under the 2023 NEC.
You could possibly use one or more of the remaining spots for a PV system, or install lug kits and continue with service conductors.