There is a difference in potential between the energized conductor and the floor. Supposing you are standing on a very thick rubber mat and further suppose we can disregard any capacitive coupling between your body and the floor (and other nearby grounded surfaces, such as pipes or metal enclosures). Thus, there is a difference in potential between your body and the energized conductor. When you touch the conductor, your body will come to the level of potential of the conductor, as Chris pointed out. You become energized. But lacking a path for current flow, your body and the conductor simply remain at the same potential as each other. You don?t feel it for the same reason that a bird feels nothing when it lands on an uninsulated transmission line. There is no difference in potential from any point in your body to any other point, thus no current flow, and thus nothing to feel.