Effect of freezing on conductivity of soils
Reducing temperature reduces electrolytic activity, and hence conductivity. The figure to the right shows this effect in terms of resistivity. Upon freezing, conductivity of water becomes that of ice, which is very low. However, freezing is rarely simple. Fresh water freezes at a higher temperature than saline water. Therefore solutes tend to become concentrated in a zone of unfrozen saline water adjacent to soil particles. Also, the electric field of cations adsorbed onto soil particles locally orients water molecules near the particle, preventing them from freezing.
The net effect is a slight and steady decrease in conductivity as temperatures approach freezing, then a levelling off through 0 degrees and a further decrease below freezing.