I had similar thing happen to me a few years ago with the Kidde ionization style detectors. It was my daughters house, so I knew I was going to have to resolve it some how. They only had three rooms and a hallway with the smoke alarms all daisy chained to go off together. The alarms would always false trigger between 3:00 AM to 4:AM. After some tracking down, and a lot of reading on the web, I started keeping track of the symptoms more. Noticed that it was always the same location (back bedroom), so I purchased a new unit. That did not help. I tried moving the detectors around. It seems that what ever detector I had in that location would would act up. Other things I tried. Checked all the wiring connections. No help. They said to seal the holes in the ceiling box where the Romex came in (to stop the air flow from attic). That did not help. Vacuumed the detectors, no help. Did find a spider in the detector once (really thought that was going to be it). Still had false triggers. Finally out of desperation, I started looking for other detector styles. There were three out there that would work with the existing system, the ionization type, the photo electric detector type, and the heat detector type. Each had it pulses and minus. To reduce the sensitivity, I changed just that detector to a photoelectric style. That seemed to do the trick. It has been two years now without a call back. My next step would have been to install the heat detector style (rate of rise).