This is where you have to dig further, see 250.68(C)(2)
I've read 250.68(C)(2), and it allows metal structural frames to be GECs. 250.52(2) also allow them to be grounding electrodes if in direct contact with the soil for at least 3.0 m vertically, such as in a basement. So, a basement frame made of stainless steel or other corrosion-resistant metals and in direct contact with the soil for at least 3.0 m will be both a grounding electrode and a GEC. 250.121(A) only prohibits an EGC from being used as a GEC, and does not prohibit GECs or grounding electrodes from being used as EGCs. So, any GEC or grounding electrode can be used as an EGC under all rules in this reply so far. It may seem like 250.121(B) prohibits structural metal frames from being used as an EGC.
However, since the NEC 2020 considers this basement metal frame as both a grounding electrode and a GEC, is it allowed to be used in essence as an EGC (for the section between the short dedicated EGC and the short GEC wire connecting it with the panelboard neutral busbar) if an EGC listed under 250.118 were bonded to it?
Also, if the same frame extended upwards to form the superstructure, but the superstructure were made of a different metal such as regular iron (which is weathering steel for the base-model option nowadays AFAIK), would the NEC 2020 still consider the superstructure to be both a grounding electrode and a grounding electrode conductor? If not, what would the NEC 2020 consider it to be? Also, would this superstructure be allowed to be used in essence as an EGC under the same conditions as the substructure besides being above-ground?