Why? What does synchronize mean, but "at the same time."
For sinusoidal waveforms:
1) Establish a common reference frame for both waves to be tested.
2) Establish T=0; though not literally time it's usually refered to as Time equal Zero.
3) Establish the positive direction of measurement in reference to T, again not literally Time.
If, when measured in the positive direction, two waveforms have equal wavelength, cross zero simultaneously, and move in the same direction, then they are synchronous.
For the residential issue, only AB or BA presents a common reference (1). AN, BN, NB, NA exclude other portions of the coil that we wish to test. Therefore those references cannot establish synchronization or phase.
When using AB as the common reference (1), we can establish T=0 (2) as the point in time when the 240V waveform crosses zero and is rising. Part (3) is the one that's throwing everyone. The real thing we're measuring here is power transfer. Both voltage and current are measureable artifacts of power transfer. As we cross T=0 the power transfer is changing according to the voltage polarity; that is, it is increasing from A to B. To measure this we are applying physical leads in a physical direction. The physical order in which the leads are applied establishes (3).
If we presume that A is physically on our left with a red lead and B is physically on our right with a black lead; then we can compare any other segment of the secondary coil with the reference wave by applying the leads to either side of the section we wish to test BUT we must maintain the physical order of the leads: that is, the red lead must always be to the left of the black lead.
Therefore to establish whether the waveforms are synchronous we can compare AN or NB to AB. But comparing BN to AB violates (3) by reversing the direction of measurement. BN would be display positive voltage during negative power flow and negative voltage during positive power flow. Thus giving erroneous results.