Mostly we wire single family and mutifamily residential. But there is occasionally some retail thrown in. So we use some MC and THHN.
Good questions, by the way!
We use it just like any type of NM-B. Same panels, breakers and devices. 310.16 causes us to upsize the wire from copper sizes: #12 cca (copper clad) for 15 amp circuits, #10 for 20 amp circuits, and #8 for 30 amp appliances like water heaters. We use aluminum SER for 240 volt circuits a lot, and it is sized like cca. It's per code to use the 75 degree column for SER (with a few exceptions), which lets us use a #6 SER for a 50 amp range.
I saw a comment earlier that said cca was only 10-20% less expensive. That may be true, but if you use much of it, like we do, that adds up. Who was the politician that once said "A billion here, a billion there, and pretty soon you're talking about real money?". Haha. I probably butchered that, but hopefully you get the idea. It is a game changer, in my opinion.