The conductor fill and ambient temperatures are the factors altering conductor ampacity whether increasing or lowering amperes, therefore after adjustments, if the wire used does not equal to the ampacity and temp of the wire to be used For the termination specification you shouldn’t be using this wire?
Lets say you have a 60C termination and 90C wire. After you run all your calculations and adjustments you discover that the ampacity at the termination is 25A and your ampacity in the conduit is 15A. These two number are not equal.
But you can still use the wire, as long as the OCPD and load are 15A or less.
The point is that these values are _maximums_ for the component that cannot be exceeded, not requirements that need to be matched between the components.
60C termination touching a 90C wire? You must limit the temperature of that junction to 60C; the lower limiting value of the two components in contact.
100A ampacity wire spliced to a 40A ampacity wire? Kosher as long as the current is 40A or less.
A 90C rated wire will operate at 60C if the current is limited to the 60C value.
What is the temperature of a 90C rated wire when no current is flowing in it? Can you pick up 90C rated wire to install it without getting burned?
-Jon