It is the rare-earth phosphor blend RE80s that are seeing the most development right now.
90+ CRI lamps have been around for decades and they exist, but they only put out about 2/3 the light output for given energy use. In my opinion, they have no use in general lighting.
There was a company called Duro-Test (the name exists, but the original company is gone) that tried to push high CRI lamps for general service lighting from retail shops to classrooms with strong marketing effort using questionable claims of benefits to push "full spectrum" lamps.
They claimed things like "more natural", better for health, ability to see better, positive effect on learning and so on with their ~5500K 90+ CRI lamps. I guess there was a time when you'd see them for general lighting. The lumen output sucked no matter what and now, you don't see these extremely inefficient lighting except in very special applications like color proofing, dental labs, museum exhibits and auto body shops.