Terminations means at equipment, like a PV inverter or a breaker or utilization equipment, yes? Then typically those terminations will be in an enclosure, so referencing Table 310.16 as the default seems perfectly reasonable to me. If you have some atypical equipment where the terminations are actually in free air, the language allows the equipment to listed for other termination ampacities.
So I'm not seeing the problem. For your outdoor free air PV application, you can use say an inverter with a conduit riser and weatherhead, and splice at the weatherhead. The conductors between the splice and the inverter would likely be governed by the termination ampacity within the inverter. While the other conductors may be in free air and governed by Table 310.17.
Cheers, Wayne