Per your notes, where 230.90(A)Ex3 applies only to 2-6, 230.90(A)Ex2 applies to 1, the below is compliant?
one set 3wire 240vCT SEC » service box » 6 ocpd's
Ampacity of SEC's = 185A
ocpd 1 = rated 200A
ocpd 2 = rated 40A
ocpd 3 = rated 40A
ocpd 4 = rated 40A
ocpd 5 = rated 40A
ocpd 6 = rated 40A
Calc load for ocpd 1 = 160A
Calc load for ocpd 2 = 30A
Calc load for ocpd 3 = 30A
Calc load for ocpd 4 = 30A
Calc load for ocpd 5 = 30A
Calc load for ocpd 6 = 30A
Calc Load Sum of 1 = 160
Rating Sum of 1 = 200
Calc Load Sum of 2-6 = 150
Rating Sum of 2-6 = 200
Unless there is some demand factor that can be applied to the common supply conductor that otherwise can't apply to individual feeders that will bring the final calculation down enough, you have more load than the ampacity of the common supply conductor.
I had an install once that had main lug I line panel (800 amp bus) as the service equipment, only had 4 breakers installed, 2- 400's 2- 125's. Don't recall exact ampacity of supply conductors but remember it was between 700 and 800.
Don't recall exact load calculation anymore but think it was only around 500 amps, and would bet majority of time never exceeds 350 amps.
Now once 2020 NEC comes into play that install wouldn't be allowed to be all in one panel anymore, but still would be able to put say a aux gutter or splice box and still install same values of OCPD's in separate enclosures or in separate vertical sections of a switchboard.
This is interesting....... doesn't NEC address SEC taps?
For overcurrent protection is says very little in 240.21 and basically has no rule(s) that is similar to those for feeders or transformer secondary conductors. They are still service conductors with potentially pretty unlimited protection from whatever they are supplied by and therefore still have limitations on how much conductor can even enter a building - though that rule is kind of vague and is interpreted differently in nearly every jurisdiction out there.